王菲 张学友 合唱:·大家帮翻译一段话,好么?一句话也可以啊

来源:百度文库 编辑:中科新闻网 时间:2024/05/09 06:37:37
To observe the uptake of the textile dyes, the clays were placed in aqueous solutions of the textile dyes and allowed to equilibrate for one day. At the end of this time, HDTMA-bentonite in the aqueous solutions of the textile dyes showed the dark colorations of the original solutions. Na-bentonite had no a_nity for the dyes. Na-clays carry a permanent negative charge in their structural framework. The hydration of Na+ ions in clays and the nature of Si-O groups impart a hydrophilic nature to the mineral surfaces. Because of this property, water is preferentially adsorbed by these surfaces, and large organic compounds cannot compete with strongly held water for adsorption sites on the clay surfaces. Thus, Na-clays are ine_ective sorbents for small organic molecules. However, it is possible to modify the surface properties of clays greatly by neutralizing the anionic framework of layer silicates by using positively charged organic species such as alkylammonim ions. In the modi_ed form (HDTMA-bentonite), the clay surface may become organophilic and interact strongly with organic compounds. Textile dyes represent a relatively large group of organic
chemicals. In an HDTMA-bentonite-dye system it is possible that adsorption may be enhanced by the hydrophobic interaction between the adsorbed dye molecule and HDTMA-bentonite. The interlamellar spacing of the HDTMA-bentonite was obtained by substracting the thickness of the clay layer from the experimentally determined basal spacing (d001). The intercalation of the HDTMA cation increased the interlamellar distances from 13.2A (Na-bentonite) to 17.9A (HDTMA-bentonite). The larger basal spacing (d001) of HDTMA-bentonite corresponds to the formation of bilayers in which the long-chained surfactant cations are in direct contact with each other10, leading to the formation of organic phases consisting mostly of the C16 hydrocarbon groups into which solutes are partitioned. Thus, the degree of sorption of dyes depends on the amount of the surfactant ions in the bentonite interlayer sites.

到观察织物染料的 ,泥土是放置在水的
织物染料和允许到平衡为了,有一天在末端的解答
这时间的,HKTMA—斑脱土在织物染料的水的解答
最初的解答。Na的表示黑暗染色—斑脱土有没有
a_nity为了染料。Na¬¬—泥土进位永久的否定负荷在他们的Na结构
水合+离子在泥土和 的性质。
O组给予亲水的性质到矿物表面,因为这 水是 吸附在这些表面,和大的有机化合物不能比 有坚强的 为了吸附位置在泥土表面,因而,Na—泥土是ine_ective吸附剂 为了小的 分子,希,它是可能的到更改的表面属性,泥土非常在抵销anionic层硅酸盐在用的结构
Positively负荷 的物种例如alkylammonim离子,在mod i_ed形状
(HDTMA—斑脱土),泥土表面可能变成organophilic和互相作用坚强地有机化合物,织物染料表现相关的 大的组
化学的,在HDTMA—斑脱土—染料系统它是可能的那吸附
可能是提高在 交互作用在中间吸附染料
分子和HDTMA—斑脱土,interlamellarHDTMA的间隔—斑脱土是获得在substracting泥土层从的厚度
实验上坚决的基础的间隔(d001)。的插入HDTMA阳离子增加的interlamellar距离从13.2A(Na—斑脱土)到17.9A(HDTMA—斑脱土)。大的基础的间隔(d001)HDTMA的—斑脱土相应bilayers在哪个长的形成—装链的。Surfactant阳离子是在径直的联系有各自的other10,领导的到 阶段由……组成主要地C16烃组的形成,到哪个溶解物的分割。因而,吸附作用的染料的度,依靠surfactant离子在斑脱土夹层位置的数量。